Biosynthesis of ascorbic acid in plants

As seen in the diagram above the biosynthetic pathway to ascorbic acid in plants but also in yeasts is quite different from that in mammalian systems. The starting material is the same, i.e. glucose but this is first converted to fructose and mannose and finally to galactose. Two different oxidases convert the L-galactose to galactono lactone and ascorbic acid, respectively.